Asymptotic Behavior of Least Energy Solutions for a Fractional Laplacian Eigenvalue Problem on ℝN

Acta Mathematica Sinica, English Series - We are interested in the existence and asymptotic behavior for the least energy solutions of the following fractional eigenvalue problem $$\left({\rm{P}}...     

Visible-light-induced,autopromoted nickel-catalyzed three-component arylsulfonation of 1,3-enynes and mechanistic insights

Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,...     

Rapid qualitative profiling and quantitative analysis of Juglandis Mandshuricae Cortex and seven flavonoids by ultra-high performance liquid chromatography–quadrupole/orbitrap high-resolution mass spectrometry

Juglandis Mandshuricae Cortex is the bark of Juglans mandshurica Maxim., which has been used as a folk medicine plant in China and India. In this study, an ultra-high performance liquid chromatography–quadrupole/orbitrap high-resolution mass spectrometry method was developed to clarify and quantify the chemical profiling of Juglandis Mandshuricae Cortex rapidly. A total of 113 compounds were characterized. Among them, seven flavonoids were simultaneously quantified in 15 min, including myricetin, myricetrin, taxifolin, kaempferol, quercetin, quercitrin, and naringenin. The method was validated for accuracy, precision, and the limits of detection and quantification. All calibration curves showed a good linear relationship (r > 0.9990) within test ranges. The intra- and inter-day relative standard deviations were less than 2.16%. Accuracy validation showed that the recovery was between 95.6 and 101.3% with relative standard deviation values below 2.85%. The validated method was successfully applied to determine the contents of seven flavones in Juglandis Mandshuricae Cortex from seven sources and the contents of these places were calculated respectively. This method provides a theoretical basis for further developing the medicinal value of Juglandis Mandshuricae Cortex.     

Correction to: Tuning working potential of silicon‑phosphorus anode via microstructure control for high‑energy lithium‑ion batteries

Journal of Solid State Electrochemistry -     

湿法消解-原子荧光法测定全血中硒

以全血样品为原料,探讨湿法消解-原子荧光法测定全血中的硒含量。血样经硝酸-高氯酸消解后,用硼氢化钠将硒还原成硒化氢,由氩气载入原子化器,产生的原子荧光强度与试液中硒元素含量在一定范围内呈正比,外标法定量。以消解效率为指标,优化样品的消解条件,测定血中硒在0-10μg/L范围内线性情况良好,相关系数为0.9992,最低检出限为0.143μg/L,相对标准偏差为1.51%-1.58%,平均加标回收率为90.86%-104.62%。血中硒的原子荧光测定法灵敏度高,精密度和稳定性好,可应用于血中硒的生物监测。     

Majorana fermions induced fast-and slow-light in a hybrid semiconducting nanowire/superconductor device

We investigate theoretically Rabi-like splitting and Fano resonance in absorption spectra of quantum dots(QDs)based on a hybrid QD-semiconducting nanowire/superconductor(SNW/SC)device mediated by Majorana fermions(MFs).Under the condition of pump on-resonance and off-resonance,the absorption spectrum experiences the conversion from Fano resonance to Rabi-like splitting in different parametric regimes.In addition,the Fano resonances are accompanied by the rapid normal phase dispersion,which will indicate the coherent optical propagation.The results indicate that the group velocity index is tunable with controlling the interaction between the QD and MFs,which can reach the conversion between the fast-and slow-light.Fano resonance will be another method to detect MFs and our research may indicate prospective applications in quantum information processing based on the hybrid QD-SNW/SC devices.     

氮分子A3Σu+、B3Пg、C3Пu电子态的高温高振转光谱研究

采用态平均（CASSCF）/高度相关多参考组（MRCI）方法，对N2分子A3Σu+、B3Пg、C3Пu电子态的势能、跃迁偶极矩进行了高度相关的精确计算．计算的势能在平衡位置附近与RKR拟合的势能曲线非常一致，获得的跃迁偶极矩与已有实验值符合很好。首次对A3Σu+、B3Пg、C3Пu电子态的振转光谱常数随振动量子数v的变化进行系统定量计算，其结果与已有的实验观测数据相符．同时，获得了N2分子第一正带系的0-1、0-2、1-0、1-2、1-3、2-0、2-1、2-3、3-0、3-1和3-2光谱带分别在300，3000，6000，10000K时的谱线强度，如1-0带在3000，6000，10000K时的高温谱线带强度分别为1.58543×10-16 cm-1/(分子 cm-2)、6.07889×10-17 cm-1/(分子 cm-2)和2.3781×10-17 cm-1/(分子 cm-2)．这些结果对N2分子进一步的理论研究、实际应用和高温大气的建模与研究具都有一定的参考价值．     

Polymeric Carbon Nitride-based Single Atom Photocatalysts for CO2 Reduction to C1 Products

Photocatalytic CO₂ reduction to C₁ fuels is considered to be an important way for alleviating increasingly serious energy crisis and environmental pollution. Due to the environment-friendly, simple preparation, easy formation of highly-stable metal-nitrogen(M-N_x) coordination bonds, and suitable band structure, polymeric carbon nitride-based single-atom catalysts(C₃N₄-based SACs) are expected to become a potential for CO₂ reduction under visible-light irradiation. In this review, we summarize the recent advancement on C₃N₄-based SACs for photocatalytic CO₂ reduction to C₁ products, including the reaction mechanism for photocatalytic CO₂ reduction to C₁ products, the structure and synthesis methods of C₃N₄-based SACs and their applications toward photocatalytic CO₂ reduction reaction(CO₂RR) for C₁ production. The current challenges and future opportunities of C₃N₄-based SACs for photoreduction of CO₂ are also discussed.     

Ergodic stationary distribution and practical application of a hybrid stochastic cholera transmission model with waning vaccine-induced immunity under nonlinear regime switching

Considering the effect of stochasticity including white noise and colored noise, this paper aims to study a hybrid stochastic cholera epidemic model with waning vaccine-induced immunity and nonlinear telegraph perturbations. First, we derive a critical value ${?}_0^C$ related to the basic reproduction number ${?}_0$ of the deterministic model. The key aim of this paper is to generalize the θ-stochastic criterion method proposed by the recent work (Han et al. in Chaos Solit Fract 140:110238, 2020) to eliminate nonlinear telegraph perturbations. Next, via constructing several θ-stochastic Lyapunov functions and using the generalized method, we further prove that the stochastic model have a unique ergodic stationary distribution under ${?}_0^C>1$. Results show that the prevention and control of cholera epidemic depend on low transmission rate and small telegraph perturbations. Finally, the corresponding numerical simulations are performed to illustrate our analytical results and a practical application on the Somalia cholera outbreak is shown at the end of this paper.     

Hudson模型适用性及储层微观建模应用*

为明确裂缝间相互作用对各向异性的影响，本文以Hudson模型为例分析了裂缝密度、裂缝倾角对地震波波场、弹性常数和Thomsen系数的影响规律，然后采用“基质-骨架-流体”组合化的方法进行了裂缝储层微观尺度的建模，并与实际测井资料进行了对比。结果表明该模型适用条件为低裂缝密度储层，二阶模型适用的裂缝密度范围比一阶模型大，但在裂缝密度过大时，二阶模型会出现不收敛的现象，模型便不再适用。裂缝储层纵横波速度随裂缝倾角增大而增大，纵波速度对裂缝倾角更为敏感。另外，在与实际测井曲线对比时，在高裂缝密度地层二阶模型的应用效果明显优于一阶模型，说明了在高裂缝密度储层考虑裂缝间的相互作用的必要性。